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本文系统综述了不同官能度Z型全氟聚醚（甲基）丙烯酸酯预聚物的合成方法（包括酯化和异氰酸酯化反应）并探讨了其在光固化树脂中的应用。研究表明，此类含氟树脂可显著降低涂层折射率（1.32～1.38）、提升疏水性（水接触角>110°），且在低光学损耗聚合物波导（传输损耗<0.2 dB/cm）和微流控芯片抗溶胀性中表现优异。未来需突破其原料Z型全氟聚醚醇的国产化合成技术，并验证其在生物医学领域的长期稳定性。
Abstract：This paper systematically reviewed the synthesis methods of Z-type perfluoropolyether(meth) acrylate prepolymers(including esterification, isocyanate reactions), and explored their applications in photocurable resins. The results demonstrated that these fluorinated resins significantly reduce coating refractive indices(1.32～1.38), enhance hydrophobicity(water contact angle >110°), and exhibit excellent performance in low-loss polymer waveguides(transmission loss <0.2 dB/cm) and anti-swelling microfluidic chips. Future efforts should focus on domestic synthesis of Z-type perfluoropolyether alcohols and validate their long-term stability in biomedical applications.
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基本信息:
中图分类号:TQ322
引用信息:
[1]刘通政,张龙,张坚.Z型全氟聚醚(甲基)丙烯酸酯预聚物的合成及应用研究进展[J].影像科学与光化学,2026,44(02):5-16+58.
基金信息:
山东省泰山产业领军人才工程资助项目（tscx202306141）
2025-01-23
2025
2025-04-02
2025-04-06
2025
1
2026-03-03
2026-03-03